Dicyanovinyl and Cyano-Ester Benzoindolenine Squaraine Dyes: The Effect of the Central Functionalization on Dye-Sensitized Solar Cell Performance

نویسندگان

  • Simone Galliano
  • Vittoria Novelli
  • Nadia Barbero
  • Alessandra Smarra
  • Guido Viscardi
  • Raffaele Borrelli
  • Frédéric Sauvage
  • Claudia Barolo
چکیده

In order to achieve a greater light absorption in the near-infrared (NIR) region with a panchromatic spectral response and to suppress the photo-isomerisation phenomenon, we herein report the design, synthesis, spectroscopic and electrochemical characterization of novel centrally functionalized symmetric benzoindolenine squaraine dyes. These molecules have shown different photoelectrical conversion properties, depending on the dicyanovinyl and cyano-ester group substitution on the squaric core unit and on the extension of the π-conjugation.

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تاریخ انتشار 2016